How-to: add an old Motorola key to a Mercedes Benz W220 S500 year 2001 using Xhorse VVDI Prog and VVDI MB Tool.
Remove key board from original key
Connect key pcb board with vvdi prog through MCU cable
In VVDI-Prog software, select 4-Immobilizer-Benz-HC05E6_REMOTE (0F82B) to read
Read data success
Save data
Open VVDI MB software, select Other Function-> Old Motorola Key
Press Load File and upload data read by vvdiprog
Read data success including key password
Save key file i.e key_Motorola.bin
Go to Read Write Key->Load Key File
Upload key file key_Motorola.bin, press Write
Write key success.
Press Identification Key and Read BE key password
Key password is correct.
Test the new key. It works.